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Alfred Werner Revisited:  The Coordination Chemistry of Anions | Accounts of Chemical Research
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    Alfred Werner Revisited:  The Coordination Chemistry of Anions
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    Department of Chemistry, University of Kansas, Lawrence, Kansas 66045
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    Accounts of Chemical Research

    Cite this: Acc. Chem. Res. 2005, 38, 8, 671–678
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    https://doi.org/10.1021/ar040071t
    Published June 25, 2005
    Copyright © 2005 American Chemical Society

    Abstract

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    A series of macrocyclic receptors were designed to probe the influence of four factors, hydrogen bonding, charge, dimensionality, and topology, on anion binding. Monocyclic and bicyclic polyammonium and polyamide receptors were synthesized from either 2,2‘-diaminodiethylamine derivatives (dien) or 2,2‘,2‘ ‘-aminoethylamine (tren) building blocks, plus aromatic or heterocyclic spacers. Supramolecular complexes of these hosts with three simple anion topologies were probed:  spherical (halides), trigonal planar (nitrate), and tetrahedral (sulfate). Results indicate a number of corollaries with transition-metal coordination chemistry in terms of binding concepts such as the chelate effect and dual valencies, as well as geometries for anion complexes that are strikingly similar to those observed in transition-metal coordination chemistry.

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    This article is cited by 677 publications.

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    Cite this: Acc. Chem. Res. 2005, 38, 8, 671–678
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    Published June 25, 2005
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