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High-Precision Catalysts:  Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes | Journal of the American Chemical Society
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    High-Precision Catalysts:  Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes
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    Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2006, 128, 35, 11344–11345
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    https://doi.org/10.1021/ja063294i
    Published August 10, 2006
    Copyright © 2006 American Chemical Society

    Abstract

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    We report the formation of high-precision catalysts using encapsulated rhodium complexes. In the current example, the encapsulated rhodium catalyst shows unprecedented high selectivity in the rhodium-catalyzed hydroformylation of internal alkenes, forming predominantly one of the branched aldehydes. This catalyst system is the first example that is able to discriminate between carbon atoms C3 and C4 in trans-3-octene.

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    Experimental details and hydroformylation of other internal olefins. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Published August 10, 2006
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